there are two concepts here (Read the official curriculum):
So, Cov (A) > Cov (L). The reason here is that Asset portfolio goes down less than Liabilities (L) when the interest rate goes up and goes up more when the interest rate goes down. this ensures A>L
However, if you have to chose from multiple asset (A) portfolios, go with the (A) asset portfolio which has the minimum Convexity. The reason here is that you want minimum dispersion of cash flows around the single liability (i.e. minimize structural risk).
Do BB #2 and #4 from CFA curriculum and the above become more clear